Deprecated: preg_match(): Passing null to parameter #2 ($subject) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/lbfactory/LBFactory.php on line 759
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 262
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: Return type of MediaWiki\Session\PHPSessionHandler::open($save_path, $session_name) should either be compatible with SessionHandlerInterface::open(string $path, string $name): bool, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php on line 181
Deprecated: Return type of MediaWiki\Session\PHPSessionHandler::close() should either be compatible with SessionHandlerInterface::close(): bool, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php on line 196
Deprecated: Return type of MediaWiki\Session\PHPSessionHandler::read($id) should either be compatible with SessionHandlerInterface::read(string $id): string|false, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php on line 210
Deprecated: Return type of MediaWiki\Session\PHPSessionHandler::write($id, $dataStr) should either be compatible with SessionHandlerInterface::write(string $id, string $data): bool, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php on line 238
Deprecated: Return type of MediaWiki\Session\PHPSessionHandler::destroy($id) should either be compatible with SessionHandlerInterface::destroy(string $id): bool, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php on line 344
Deprecated: Return type of MediaWiki\Session\PHPSessionHandler::gc($maxlifetime) should either be compatible with SessionHandlerInterface::gc(int $max_lifetime): int|false, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php on line 365
Deprecated: strcasecmp(): Passing null to parameter #1 ($string1) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/CookieSessionProvider.php on line 101
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 262
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: Return type of MediaWiki\Session\Session::count() should either be compatible with Countable::count(): int, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/Session.php on line 593
Deprecated: Return type of MediaWiki\Session\Session::current() should either be compatible with Iterator::current(): mixed, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/Session.php on line 599
Deprecated: Return type of MediaWiki\Session\Session::next() should either be compatible with Iterator::next(): void, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/Session.php on line 611
Deprecated: Return type of MediaWiki\Session\Session::key() should either be compatible with Iterator::key(): mixed, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/Session.php on line 605
Deprecated: Return type of MediaWiki\Session\Session::valid() should either be compatible with Iterator::valid(): bool, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/Session.php on line 623
Deprecated: Return type of MediaWiki\Session\Session::rewind() should either be compatible with Iterator::rewind(): void, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/Session.php on line 617
Deprecated: Return type of MediaWiki\Session\Session::offsetExists($offset) should either be compatible with ArrayAccess::offsetExists(mixed $offset): bool, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/Session.php on line 633
Deprecated: Return type of & MediaWiki\Session\Session::offsetGet($offset) should either be compatible with ArrayAccess::offsetGet(mixed $offset): mixed, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/Session.php on line 646
Deprecated: Return type of MediaWiki\Session\Session::offsetSet($offset, $value) should either be compatible with ArrayAccess::offsetSet(mixed $offset, mixed $value): void, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/Session.php on line 656
Deprecated: Return type of MediaWiki\Session\Session::offsetUnset($offset) should either be compatible with ArrayAccess::offsetUnset(mixed $offset): void, or the #[\ReturnTypeWillChange] attribute should be used to temporarily suppress the notice in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/Session.php on line 661
Deprecated: Message implements the Serializable interface, which is deprecated. Implement __serialize() and __unserialize() instead (or in addition, if support for old PHP versions is necessary) in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/language/Message.php on line 161
Deprecated: MapCacheLRU implements the Serializable interface, which is deprecated. Implement __serialize() and __unserialize() instead (or in addition, if support for old PHP versions is necessary) in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/MapCacheLRU.php on line 38
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: RawMessage implements the Serializable interface, which is deprecated. Implement __serialize() and __unserialize() instead (or in addition, if support for old PHP versions is necessary) in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/RawMessage.php on line 35
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: Creation of dynamic property Parser::$scribunto_engine is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/extensions/Scribunto/includes/common/Hooks.php on line 81
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Warning: Cannot modify header information - headers already sent by (output started at /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php:35) in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/changes/ChannelFeed.php on line 95
Warning: Cannot modify header information - headers already sent by (output started at /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php:35) in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/changes/ChannelFeed.php on line 100
Warning: Cannot modify header information - headers already sent by (output started at /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php:35) in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/WebResponse.php on line 74
Warning: Cannot modify header information - headers already sent by (output started at /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php:35) in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/WebResponse.php on line 74
Warning: Cannot modify header information - headers already sent by (output started at /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php:35) in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/WebResponse.php on line 74
Warning: Cannot modify header information - headers already sent by (output started at /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/session/PHPSessionHandler.php:35) in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/WebResponse.php on line 74
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578 http://www.mysolutions.tecnico.ulisboa.pt//mysolutions/wiki/index.php?action=history&feed=atom&title=Equa%C3%A7%C3%A3o_de_van_der_WaalsEquação de van der Waals - Histórico de revisões2025-08-23T08:36:26ZHistórico de edições para esta página nesta wikiMediaWiki 1.35.2 Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
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Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578 http://www.mysolutions.tecnico.ulisboa.pt//wiki/index.php?title=Equa%C3%A7%C3%A3o_de_van_der_Waals&diff=683&oldid=prevIst172788 em 18h04min de 20 de dezembro de 20152015-12-20T18:04:31Z<p></p>
<table class="diff diff-contentalign-left diff-editfont-monospace" data-mw="interface">
<col class="diff-marker" />
<col class="diff-content" />
<col class="diff-marker" />
<col class="diff-content" />
<tr class="diff-title" lang="pt">
<td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Revisão anterior</td>
<td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revisão das 18h04min de 20 de dezembro de 2015</td>
</tr><tr><td colspan="2" class="diff-lineno" id="mw-diff-left-l26" >Linha 26:</td>
<td colspan="2" class="diff-lineno">Linha 26:</td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>b) Indique, justificando, qual das duas substâncias tem um ponto de ebulição mais baixo à pressão atmosférica.</div></td><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>b) Indique, justificando, qual das duas substâncias tem um ponto de ebulição mais baixo à pressão atmosférica.</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'>−</td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>c) Indique qual das duas substâncias tem moléculas maiores. Calcule o valor do raio do átomo de Hélio no <del class="diffchange diffchange-inline">quadr </del>do modelo de VDW.</div></td><td class='diff-marker'>+</td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>c) Indique qual das duas substâncias tem moléculas maiores. Calcule o valor do raio do átomo de Hélio no <ins class="diffchange diffchange-inline">quadro </ins>do modelo de VDW.</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>d) Mostre que os parâmetros críticos de VDW verificam a expressão</div></td><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>d) Mostre que os parâmetros críticos de VDW verificam a expressão</div></td></tr>
<tr><td colspan="2" class="diff-lineno" id="mw-diff-left-l32" >Linha 32:</td>
<td colspan="2" class="diff-lineno">Linha 32:</td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>\( p_c V_c = \frac{3}{8} n R T_c \),</div></td><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>\( p_c V_c = \frac{3}{8} n R T_c \),</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'>−</td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>onde\( T_c \) é a temperatura crítica do sistema.</div></td><td class='diff-marker'>+</td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>onde \( T_c \) é a temperatura crítica do sistema.</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>e) Calcule \( T_c \) para o Hélio e para água e compare o comportamento destes sistemas à temperatura ambiente (300 K).</div></td><td class='diff-marker'> </td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>e) Calcule \( T_c \) para o Hélio e para água e compare o comportamento destes sistemas à temperatura ambiente (300 K).</div></td></tr>
</table>Ist172788 Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578
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Deprecated: strlen(): Passing null to parameter #1 ($string) of type string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/rdbms/database/Database.php on line 578 http://www.mysolutions.tecnico.ulisboa.pt//wiki/index.php?title=Equa%C3%A7%C3%A3o_de_van_der_Waals&diff=682&oldid=prevIst172788: Criou a página com "O Hélio e a água são corretamente descritos, na transição líquido-vapor, pela equação de van der Waals (VDW) \( \left( p + \frac{n^2 a}{V^2} \right) (V - n b) = n R..."2015-12-20T18:03:27Z<p>Criou a página com "O Hélio e a água são corretamente descritos, na transição líquido-vapor, pela equação de van der Waals (VDW) \( \left( p + \frac{n^2 a}{V^2} \right) (V - n b) = n R..."</p>
<p><b>Página nova</b></p><div>O Hélio e a água são corretamente descritos, na transição líquido-vapor, pela equação de van der Waals (VDW)<br />
<br />
\( \left( p + \frac{n^2 a}{V^2} \right) (V - n b) = n R T \),<br />
<br />
a qual conduz às seguintes expressões para a pressão crítica \( p_c \) e para o volume crítico \( V_c \):<br />
<br />
\( p_c = \frac{a}{27b^2} \),<br />
<br />
\( V_c = 3 n b \).<br />
<br />
Para o Hélio tem-se<br />
<br />
\( a = 0,0340 \times 10^6 \) atm cm<sup>6</sup> mol<sup>-2</sup>,<br />
<br />
\( b = 23,40 \) cm<sup>3</sup> mol<sup>-1</sup>,<br />
<br />
e para a água<br />
<br />
\( a = 5,460 \times 10^6 \) atm cm<sup>6</sup> mol<sup>-2</sup>,<br />
<br />
\( b = 30,45 \) cm<sup>3</sup> mol<sup>-1</sup>,<br />
<br />
<br />
a) Indique qual das duas substâncias tem forças de interação molecular mais intensas. Calcule a relação de ordem de grandeza entre as suas intensidades, considerando que os seus átomos/moléculas têm dimensões semelhantes.<br />
<br />
b) Indique, justificando, qual das duas substâncias tem um ponto de ebulição mais baixo à pressão atmosférica.<br />
<br />
c) Indique qual das duas substâncias tem moléculas maiores. Calcule o valor do raio do átomo de Hélio no quadr do modelo de VDW.<br />
<br />
d) Mostre que os parâmetros críticos de VDW verificam a expressão<br />
<br />
\( p_c V_c = \frac{3}{8} n R T_c \),<br />
<br />
onde\( T_c \) é a temperatura crítica do sistema.<br />
<br />
e) Calcule \( T_c \) para o Hélio e para água e compare o comportamento destes sistemas à temperatura ambiente (300 K).<br />
<br />
<br />
[-> METADATA NÃO REALIZADA <-]</div>Ist172788 Deprecated: str_replace(): Passing null to parameter #3 ($subject) of type array|string is deprecated in /afs/ist.utl.pt/groups/mysolutions/web/wiki/includes/libs/objectcache/MediumSpecificBagOStuff.php on line 893
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